Dr Stuart Robertson

Senior Lecturer

Pure and Applied Chemistry

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Personal statement

I am currently a Senior Lecturer having held a Chancellor's Fellowship and been the recipient of a five-year Royal Society of Edinburgh BP Trust personal research Fellowship hosted here at Strathclyde (2012-2017). My main research focus is on both homo- and heterometallic main group and transition metal complexes (particularly alkyls and amides), and how they can be used practically in socially and economically important applications. We are especially interested in the s-block metals such as lithium, sodium and magnesium and the novel chemistry that can be obtained when these are paired with environmentally benign metals of high natural abundance such as zinc, aluminium and iron. These metals are considerably cheaper than precious transition metals and, once more is understood about their chemistry, they have the potential to replace the heavy metals in diverse areas including catalysis, while their lower molecular weight makes them attractive in the field of energy storage materials. At the applied end, we are currently focused on the pairing of these elements for the targeted synthesis of electrolyte complexes for post-lithium batteries. Mg for example shows considerable promise here due to its divalency and considerable natural abundance. We are also interested in dihydropyridine complexes and their application as soluble surrogate metal hydrides in both stoichiometric and catalytic applications.

We work closely with other academic groups both internally and externally and have also contributed to a wide range of projects with industrial partners including Tendeka, Invinity, Stortera and also with colleagues at the National Physical Laboratory. Our strong links with the Chemical & Process Engineering Department at Strathclyde has allowed us to support many students from our joint Chemistry and Chemical Engineering Degree stream.

I received MChem (Hons) and Phd degrees from the University of St Andrews in 2002 and 2006 respectively, the latter studying the coordination chemistry of polyaromatic disulfide ligands in the group of Prof Derek Woollins. Following this I joined the group of Prof Tris Chivers at the University of Calgary, Canada for a three year postdoctoral spell researching the synthesis, coordination and redox chemistry of group 16 imidodiphosphinate ligands. I then returned home to my native Scotland to take up a postdoctoral position under the direction of Prof Robert Mulvey at Strathclyde where I studied main group bimetallic complexes.

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Area of Expertise

  • Organometallic chemistry
  • Inert atmopshere reaction manipulation
  • Single crystal X-ray diffraction
  • Multinuclear 1D and 2D NMR spectroscopy
  • Reaction design

Prize And Awards

Royal Society of Edinburgh BP Trust Fellowship
Recipient
1/10/2012

More prizes and awards

Qualifications

Experience and Qualifications

  • Senior Lecturer, University of Strathclyde, 2019-present
  • Chancellor's Fellow and Lecturer, University of Strathclyde, 2015-2019
  • Royal Society of Edinburgh BP Trust Research Fellow, University of Strathclyde, 2012-2017
  • PDRA (Prof. R.E. Mulvey Group), University of Strathclyde, 2009-2012
  • PDRA (Prof. T. Chivers Group), University of Calgary, 2006-2009
  • PhD (Prof. J.D. Woollins Group), University of St Andrews, 2002-2006
  • MChem (Hons) 1st class, Chemistry and Advanced Chemistry, University of St Andrews, 1998-2002
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Publications

Isomeric effects in lithium dihydropyridinate chemistry : the privileged status of the tert‐butyl isomer
Horsley Downie Thomas M, Byrne Keelan M, Kennedy Alan R, Macdonald Peter A, Shanfrezan Diney S, Thomson Ailish, Krämer Tobias, Mulvey Robert E, Robertson Stuart D
Chemistry - A European Journal (2025)
https://doi.org/10.1002/chem.202500780
Diverse multinuclear alkali metallated (Li, Na, K, Rb, Cs) family of the 1,3,5‐tris‐2‐aminopyridyl‐2,4,6‐triethylbenzene framework
Lynch Jennifer R, Navarro Marta, Kennedy Alan R, Robertson Stuart D, Mulvey Robert E, Hernán‐Gómez Alberto
Chemistry - A European Journal Vol 31 (2025)
https://doi.org/10.1002/chem.202403544
Magnesium 4, 5, and 6 coordinate complexes with ligands bound via sp or sp2 hybridized atoms
Rae Annabel, Kennedy Alan R, Robertson Stuart D
Polyhedron Vol 266 (2025)
https://doi.org/10.1016/j.poly.2024.117257
Mechanistic insight into alkali-metal mediation of styrene transfer hydrogenation : a DFT study
Byrne Keelan M, Robertson Stuart D, Mulvey Robert E, Kraemer Tobias
ChemCatChem Vol 16 (2024)
https://doi.org/10.1002/cctc.202400655
Recent advances in in situ / operando characterization of lithium–sulfur batteries
Leckie Thomas J, Robertson Stuart D, Brightman Edward
Energy Advances Vol 3, pp. 2479-2502 (2024)
https://doi.org/10.1039/d4ya00416g
Synthesis and structure of heavy alkali metal pentalenides
Sanderson Hugh, Banerjee Sumanta, Kaur Mandeep, Kennedy Alan, Kociok-Köhn Gabriele, Hintermair Ulrich, Robertson Stuart
ZAAC Vol 650 (2024)
https://doi.org/10.1002/zaac.202400039

More publications

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Research Interests

  • Main group chemistry - synthesis and catalysis
  • Bimetallic cooperativity
  • Non-aqueous electrolytes
  • Dihydropyridines
  • Alkyl and amide ligands
  • Deep eutectic solvents and ionic liquids
  • Sustainable batteries

Professional Activities

Development and Applications of Lithium and Sodium Dihydropyridines
Speaker
14/2/2025
Strategic Themes: EPSRC Critical Mass Programmes to Drive a Sustainable Future
Participant
30/1/2025

More professional activities

Projects

Rational Development of Organocaesium Chemistry
Mulvey, Robert (Principal Investigator) Robertson, Stuart (Co-investigator)
01-Jan-2024 - 31-Jan-2028
DTP 2224 University of Strathclyde | Leckie, Thomas
Brightman, Edward (Principal Investigator) Robertson, Stuart (Co-investigator) Leckie, Thomas (Research Co-investigator)
01-Jan-2023 - 01-Jan-2027
Heat Utilisation via Thermally Regenerative Electrochemical System (HEATHER)
Brightman, Edward (Principal Investigator) Robertson, Stuart (Co-investigator)
28-Jan-2023 - 23-Jan-2026
Targeted design and testing of novel magnesium battery electrolytes for safe, high energy density storage
Robertson, Stuart (Principal Investigator)
01-Jan-2022 - 31-Jan-2023
Doctoral Training Partnership 2020-2021 University of Strathclyde | Lynch, Jennifer
Mulvey, Robert (Principal Investigator) Robertson, Stuart (Co-investigator) Lynch, Jennifer (Research Co-investigator)
01-Jan-2020 - 17-Jan-2024
Propelling Sodium to the Forefront of Metallation Chemistry
Mulvey, Robert (Principal Investigator) Robertson, Stuart (Co-investigator)
01-Jan-2020 - 31-Jan-2024

More projects

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Contact

Dr Stuart Robertson
Senior Lecturer
Pure and Applied Chemistry

Email: stuart.d.robertson@strath.ac.uk
Tel: 548 2642